Surface Degradation
A chemical reaction converts the metallic tin surface of a circuit board pad into tin oxides when exposed to oxygen or humidity. The development of immersion tin oxidation reduces the metallic surface available for solder wetting during the assembly process. This chemical change is particularly rapid when board panels are subjected to multiple thermal cycles in reflow ovens.
The resulting oxide layer is highly resistant to standard rosin fluxes.
Solderability Impact
Wetting of the surface mount pads is inhibited by the high melting point of the oxidized outer skin. If immersion tin oxidation is advanced, the molten solder will not coalesce on the pad, leading to non wetting defects or dewetted joints. This issue is prominent in double sided reflow assembly where the first pass exposes the second side pads to intense heat in an oxygen rich environment.
Solder paste cannot easily penetrate the tin oxide barrier without highly active and corrosive flux chemistry. This problem is mitigated by using nitrogen inerting during the reflow process to prevent further oxidation of the exposed pads.
Storage Protection
Protective packaging and controlled warehouse conditions are required to limit the rate of pad degradation. Intermetallic growth between the underlying copper and the thin tin layer also accelerates when the boards are stored in warm environments. Boards finished with immersion tin must be used within a specified window to ensure reliable joint formation.
Vacuum sealing with desiccant is the standard method to maintain solderability over time.