Gas Trapping
Pockets of empty space formed within solder joints during the reflow process arise when trapped moisture or volatile organic compounds from the board or flux vaporize and cannot escape. An outgassing void usually occurs in plated through-holes or under large surface-mount components where the escape path for gas is restricted. As the solder melts, the vaporized material expands rapidly and forms bubbles that remain trapped as the alloy solidifies.
This phenomenon is particularly common when circuit boards are not baked prior to assembly to remove absorbed moisture. The result is a weakened physical connection that may pass initial electrical tests but fail in the field under thermal stress.
Vaporization Behavior
Moisture absorption in the laminate material or the solder mask is the primary source of the expanding vapor. During the high-temperature reflow cycle, this moisture rapidly converts to steam, generating high localized pressure that forces its way through the molten solder. If the plating in the through-hole has micro-voids or pinholes, the moisture from the fiberglass core is drawn directly into the solder joint.
This behavior can be minimized by maintaining a slow reflow ramp rate to allow the moisture to escape before the solder liquefies.
Quality Defect
The presence of these internal cavities reduces the electrical and thermal conductivity of the joint. In severe cases, the reduction in cross-sectional area compromises the mechanical strength of the connection, leading to early fatigue failure under thermal cycling or vibration. Quality standards such as IPC-A-610 define the maximum allowable limits for these empty spaces, often restricting them to less than twenty-five percent of the joint area in critical applications.