Electroless Deposition
Metal coating of a printed circuit board substrate involves an immersion process creating a barrier against oxidation. Electroless nickel immersion gold or enig finish forms this layer by depositing a thin film of phosphorus-doped nickel followed by a nanometre scale gold coating. The nickel serves as a diffusion barrier preventing copper migration into the surface connection, while the gold protects the nickel from corrosion before component attachment.
This architecture provides a flat surface geometry suitable for fine pitch surface mount components and wire bonding operations.
Surface Metallurgy
Chemical displacement reactions drive the formation of the gold layer onto the nickel surface during the production sequence. Bath parameters including pH, temperature and metal ion concentration dictate the deposit quality during the plating cycle. Improper bath maintenance leads to black pad, a defect where excessive corrosion of the nickel surface occurs during the gold immersion phase.
Such degradation creates brittle solder joints that crack under thermal or mechanical loading.
Performance Constraint
High frequency signal transmission requirements dictate the limits of this metallic finish due to the magnetic properties of nickel. Skin effect losses increase because the nickel layer possesses higher electrical resistance compared to copper or solder. Designers account for these signal attenuation effects when specifying the finish for radio frequency boards.
The chemical robustness of the finish allows for extended shelf life during storage and assembly cycles without requiring additional oxidative protection.